Sonochemistry .2. Effects of ultrasounds on homogeneous chemical reactions and in environmental detoxification

被引:54
作者
Colarusso, P
Serpone, N
机构
[1] Lab. Pure Appl. Studs. Catalys., E., Dept. of Chemistry and Biochemistry, Concordia University, Montreal
关键词
D O I
10.1163/156856796X00386
中图分类号
O6 [化学];
学科分类号
0703 [化学];
摘要
Sonication of aqueous solutions causes cavitation in the liquid which results in the formation of H . and . OH radical species that can be used to reduce or oxidize certain chemical compounds. This article focuses on the effect of ultrasounds in homogeneous reactions to examine the type of chemistry that ensues. It also deals with a rather novel method of using ultrasounds in combination with photochemical methods of inducing chemical reactions; this sonophotochemical technique remains to be explored and exploited. Finally, we examine and explore the potential utilization of ultrasounds to convert environmental hazardous substances into more benign substrates, or better still to mineralize organics into carbon dioxide.
引用
收藏
页码:61 / 89
页数:29
相关论文
共 35 条
[1]
A MILD AND EFFICIENT SONOCHEMICAL BROMINATION OF ALKENES USING TETRABUTYLAMMONIUM TRIBROMIDE [J].
BERTHELOT, J ;
BENAMMAR, Y ;
LANGE, C .
TETRAHEDRON LETTERS, 1991, 32 (33) :4135-4136
[2]
CHEN JW, 1971, EPA17020 ECI
[3]
CHEN JW, 1975, 1ST INT S OZ WAST TR
[4]
SONOCHEMICAL DESTRUCTION OF CHLORINATED HYDROCARBONS IN DILUTE AQUEOUS-SOLUTION [J].
CHEUNG, HM ;
BHATNAGAR, A ;
JANSEN, G .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 1991, 25 (08) :1510-1512
[5]
EFFECT OF CERTAIN VARIABLES ON ULTRASONIC CLEAVAGE OF PHENOL AND OF PYRIDINE [J].
CURRELL, DL ;
NAGY, S ;
WILHEIM, G .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1963, 85 (02) :127-&
[6]
CURRELL DL, 1958, J AM CHEM SOC, V80, P207
[7]
D'Silva A. P., 1990, POLYCYCL AROMAT COMP, V1, P125
[8]
SONICATION-INDUCED REDUCTIVE DECARBOXYLATION OF THIOHYDROXAMIC ESTERS [J].
DAUBEN, WG ;
BRIDON, DP ;
KOWALCZYK, BA .
JOURNAL OF ORGANIC CHEMISTRY, 1990, 55 (01) :376-378
[9]
SONICATION-INDUCED HALOGENATIVE DECARBOXYLATION OF THIOHYDROXAMIC ESTERS [J].
DAUBEN, WG ;
BRIDON, DP ;
KOWALCZYK, BA .
JOURNAL OF ORGANIC CHEMISTRY, 1989, 54 (26) :6101-6106
[10]
ETEMADMOGHADAM G, 1989, TETRAHEDRON LETT, V42, P5965