μ-Oxo-bis[(2,3,12,13-tetrabromo-5,10,15,20-tetraphenylporphyrinato)-iron(III)] bis(dichloromethane) solvate

被引：11

作者：

Li, M ^{[1
]}

Shang, MY ^{[1
]}

Duval, HF ^{[1
]}

Scheidt, WR ^{[1
]}

机构：

[1] Univ Notre Dame, Dept Chem & Biochem, Notre Dame, IN 46556 USA

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 2000年 / 56卷 / 56期

关键词：

D O I：

10.1107/S0108270100010222

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The precise structure of the title compound, [Fe2O(C44H24Br4N4)(2)]. 2CH(2)Cl(2), is reported. The Fe-N distances are non-equivalent in pairs because of the asymmetric peripheral substitution; the values are 2.098 Angstrom to the brominated rings and 2.041 Angstrom to the other two rings. The Fe-O bond distance is 1.7583 (4) Angstrom. The molecule has required twofold symmetry so that there is one unique porphyrin macrocycle and one Fe-O bond length in contrast to a previous report on the same species.

引用

页码：1206 / 1207

页数：2

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