Chiroptical sensing of asymmetric hydrocarbons using a homochiral supramolecular Box from a bismetalloporphyrin rotamer

被引：46

作者：

Aimi, Junko

Oya, Kazumasa

Tsuda, Akihiko

Aida, Takuzo

机构：

[1] Univ Tokyo, Sch Engn, Dept Chem & Biotechnol, Bunkyo Ku, Tokyo 1138656, Japan

[2] JST, PRESTO, Kawaguchi, Saitama 3320012, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 12期

关键词：

chiroptical sensing; hydrocarbons; molecular recognition; porphyrinoids; self-assembly;

D O I：

10.1002/anie.200604330

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) The surrounding shapes the box: The zinc porphyrin dimer 1 bearing pyridyl groups can chiroptically sense an asymmetric hydrocarbon, such as limonene, by forming the homochiral box-shaped tetrameric assembly BOX⊥. As the BOX⊥ formed is enantiomerically enriched, the optical purity as well as the absolute configuration of the solvent limonene can be determined. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

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页码：2031 / 2035

页数：5

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