To "dress" the "naked" acetylide with metal complexes: How and why?

被引：59

作者：

Rosenthal, U ^{[1
]}

机构：

[1] Univ Rostock EV, Leibniz Inst Organ Katalyse, D-18055 Rostock, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 16期

关键词：

alkyne ligands; alkynes; carbides; cluster compounds; coordination modes;

D O I：

10.1002/anie.200201619

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The high mobility of the C22- ligand in trinuclear complexes of the type [M]3C2 (shown schematically) and alkynyl-bridged [M]2C2R complexes provides information for attaining a better understanding of the topomerization processes of alkyne complexes and alkynes via vinylidene complexes [M]=C=CR2 and vinylidenes:C=CR2, respectively, in which the carbon atoms exchange their positions.

引用

页码：1794 / 1798

页数：5

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