[MoO2(acac)2], a versatile precursor for diazenido- and hydrazido-complexes

被引：29

作者：

Carrillo, D ^{[1
]}

机构：

[1] Pontificia Univ Catolica Valparaiso, Inst Quim, Lab Quim Inorgan, Valparaiso, Chile

来源：

COMPTES RENDUS DE L ACADEMIE DES SCIENCES SERIE II FASCICULE C-CHIMIE | 2000年 / 3卷 / 03期

关键词：

molybdenum; diazenido; hydrazido(2-); hydrazido(1-); alkoxo; dinuclear complexes; tetranuclear complexes;

D O I：

10.1016/S1387-1609(00)00137-7

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In this review, we present the most significant aspects of die reactivity of [MoO2(acac)(2)] toward (i) phenylhydrazine drazine and its p-substituted derivatives, R-p-C6H4NHNH2 (R= Me, MeO, Cl, NO2), (ii) N,N-disubstituted hydrazines, PhRNNH2 (R = Me, Ph), and (iii) N,N-disubsrituted hydrazinium halides, PhRNNH3+ X- (R = Me, Ph; X = CL; Br, I) in alcohols and acetonitrile. In particular, we emphasize the versatility of [MoO2(acac)(2)] as a precursor for a number of mono-, di- and tetranuclear organodinitrogen molybdenum complexes containing diazenido, NNR, hydrazido(2-), NNRR', and hydrazido(1-), NHNRR', ligands. (C) 2000 Acedemie des sciences / Editions scientifiques et medicales Elsevier SAS.

引用

页码：175 / 181

页数：7

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