(1,3-butadiynyl-C1)(η5-cyclopentadienyl)(triphenylphosphine-P)nickel(II)

被引：15

作者：

Gallagher, JF ^{[1
]}

Butler, P

Manning, AR

机构：

[1] Dublin City Univ, Sch Chem Sci, Dublin 9, Ireland

[2] Natl Univ Ireland Univ Coll Dublin, Dept Chem, Dublin 4, Ireland

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1998年 / 54卷

关键词：

D O I：

10.1107/S0108270197016478

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title compound, [Ni(Cp)(PPh3)(C=C-C=C-H)] or [Ni(C4H)(C5H5)(C18H15P)], has metal-ligand dimensions of Ni-P 2.1410 (4), Ni-C 1.8383 (15) Angstrom and P-Ni-C 93.47 (5)degrees, and principal alkyne dimensions of C=C 1.212 (2) and 1.187 (3) Angstrom, and C=C-C 177.94 (19) and 179.5 (2)degrees, Intra- and intermolecular C-H ... C=C interactions are present with the shortest C ... C distance being 3.198 Angstrom.

引用

页码：342 / 345

页数：4

共 16 条

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