Self-assembled flower-like hierarchical spheres and nanobelts of manganese oxide by hydrothermal method and morphology control of them

被引:64
作者
Yan, D.
Yan, P. X. [1 ]
Yue, G. H.
Liu, J. Z.
Chang, J. B.
Yang, Q.
Qu, D. M.
Geng, Z. R.
Chen, J. T.
Zhang, G. A.
Zhuo, R. F.
机构
[1] Lanzhou Univ, Sch Phys Sci & Technol, Lanzhou 730000, Gansu, Peoples R China
[2] Chinese Acad Sci, Lanzhou Inst Chem & Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China
基金
中国国家自然科学基金;
关键词
D O I
10.1016/j.cplett.2007.04.027
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Self-assembled 3D flower-like hierarchical spheres composed of small nanosheets and nanobelts of manganese oxide were prepared by a simple hydrothermal method at 125 degrees C and 200 degrees C, respectively in aqueous solution, without the assistance of any templates and SDAs. A mechanism involving two competitive factors, temperature and Coulomb interaction, was proposed to understand their formation. Morphology control of the product can be easily achieved by adjusting the reaction temperature according to this mechanism, which was supported by other parallel experiments. The product was characterized by XRD, TEM, FESEM and BET surface area analysis was also carried out. (C) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码:134 / 138
页数:5
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