Stable non-N-heterocyclic carbenes (non-NHC): recent progress

被引：152

作者：

Canac, Y ^{[1
]}

Soleilhavoup, M ^{[1
]}

Conejero, S ^{[1
]}

Bertrand, G ^{[1
]}

机构：

[1] Univ Calif Riverside, Dept Chem, CNRS,UMR 2282, Joint Res Lab, Riverside, CA 92521 USA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2004年 / 689卷 / 24期

关键词：

carbene;

D O I：

10.1016/j.jorganchem.2004.02.005

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This account summarizes the results that have been obtained by our group since 2000 in the area of stable singlet acyclic carbenes. It includes aryl- and alkyl-(phosphino)carbenes, aryl(amino)carbenes, and (amino)(phosphino)carbenes. Our most recent achievements, the transformation of stable carbenes into other stable carbenes are also discussed, along with preliminary results concerning the ligand properties of these species. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：3857 / 3865

页数：9

共 64 条

[1] THE NATURE OF FIELD EFFECTS AND THEIR FALL-OFF WITH DISTANCE - THE ACIDITY OF SUBSTITUTED QUINUCLIDINIUM AND BICYCLOOCTYLAMMONIUM IONS
ADCOCK, W
ANVIA, F
BUTT, G
COOK, A
DUGGAN, P
GROB, CA
MARRIOTT, S
ROWE, J
TAAGEPERA, M
TAFT, RW
TOPSOM, RW
[J]. JOURNAL OF PHYSICAL ORGANIC CHEMISTRY, 1991, 4 (06) : 353 - 360
[2] Chelated iridium(III) bis-carbene complexes as air-stable catalysts for transfer hydrogenation
Albrecht, M
Miecznikowski, JR
Samuel, A
Faller, JW
Crabtree, RH
[J]. ORGANOMETALLICS, 2002, 21 (17) : 3596 - 3604
[3] Alder RW, 2002, CARBENE CHEMISTRY, P153
[4] Stable aminooxy- and aminothiocarbenes
Alder, RW
Butts, CP
Orpen, AG
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (44) : 11526 - 11527
[5] Bis(diisopropylamino)carbene
Alder, RW
Allen, PR
Murray, M
Orpen, AG
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1996, 35 (10): : 1121 - 1123
[6] Diaminocarbenes;: Calculation of barriers to rotation about Ccarbene-N bonds, barriers to dimerization, proton affinities, and 13C NMR shifts
Alder, RW
Blake, ME
Oliva, JM
[J]. JOURNAL OF PHYSICAL CHEMISTRY A, 1999, 103 (50) : 11200 - 11211
[7] [Anonymous], 2002, Carbene Chemistry: From Fleeting Intermediates to Powerful Reagents
[8] A STABLE CRYSTALLINE CARBENE
ARDUENGO, AJ
HARLOW, RL
KLINE, M
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (01) : 361 - 363
[9] A STABLE DIAMINOCARBENE
ARDUENGO, AJ
GOERLICH, JR
MARSHALL, WJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (44) : 11027 - 11028
[10] Arduengo AJ, 1997, LIEBIGS ANN-RECL, P365

← 1 2 3 4 5 6 7 →