Study of cyclic borinates obtained from piperidine- and piperazine alcohols by spectroscopic methods and X-ray crystallography

被引：26

作者：

Hopfl, H

Farfan, N

Castillo, D

Santillan, R

Gutierrez, A

Daran, JC

机构：

[1] Univ Autonoma Estado Morelos, Ctr Invest Quim, Cuernavaca 62210, Morelos, Mexico

[2] Inst Politecn Nacl, Ctr Invest & Estudios Avanzados, Dept Quim, Mexico City 07000, DF, Mexico

[3] Univ Autonoma Metropolitana Ixtapalapa, Unidad Ixtapalapa, Lab Resonancia Magnet Nucl, Ixtapalapa 09340, Mexico

[4] CNRS, Chim Coordinat Lab, F-31077 Toulouse, France

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1998年 / 553卷 / 1-2期

关键词：

borinates; boron complexes; piperidine- and piperazine alcohols; coordinative N -> B bond; X-ray crystallography;

D O I：

10.1016/S0022-328X(97)00636-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of eleven new 2-aminoethyl- and 3-aminopropyl borinate derivatives with a coordinative N --> B bond has been synthesized by condensation reactions between piperidine-as well as piperazine alcohols and diphenylborinic acid. The products obtained are analogous to N-spiro compounds and bicyclic systems and have been characterized by spectroscopic methods and X-ray crystallography. Thereby the N --> B bond and the geometry of this new heterocyclic systems have been studied in more detail. (C) 1998 Elsevier Science S.A.

引用

收藏

页码：221 / 239

页数：19

相关论文

共 57 条

[1] STRUCTURAL STUDIES OF ORGANOBORON COMPOUNDS .40. 4,7-DICYCLOHEXYL-2,2,5,6-TETRAPHENYL- 1,3-DIOXA-4-AZA-7-AZONIA-2-BORATACYCLOHEPTANE [J].

AMT, H ;

KLIEGEL, W ;

RETTIG, SJ ;

TROTTER, J .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1990, 68 (10) :1797-1802

[2] BORON-CONTAINING ANTI-BACTERIAL AGENTS - EFFECTS ON GROWTH AND MORPHOLOGY OF BACTERIA UNDER VARIOUS CULTURE CONDITIONS [J].

BAILEY, PJ ;

COUSINS, G ;

SNOW, GA ;

WHITE, AJ .

ANTIMICROBIAL AGENTS AND CHEMOTHERAPY, 1980, 17 (04) :549-553

[3] CONFORMATIONS OF CYCLOHEPTANE [J].

BOCIAN, DF ;

PICKETT, HM ;

ROUNDS, TC ;

STRAUSS, HL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (04) :687-695

[4] PROTON MAGNETIC RESONANCE STUDIES OF CYCLIC COMPOUNDS .V. CHEMICAL SHIFTS OF 2,6-PROTONS IN C-ALKYL- AND N-ALKYLPIPERIDINES [J].

BOOTH, H ;

LITTLE, JH .

TETRAHEDRON, 1967, 23 (01) :291-&

[5]

BOOTH H, 1969, PROGR NMR SPECTROSCO, V5, P333

[6] STUDIES IN STEREOCHEMISTRY .6. THE EFFECT OF F-STRAIN ON THE RELATIVE BASE STRENGTHS OF AMMONIA AND THE METHYLAMINES [J].

BROWN, HC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1945, 67 (03) :378-380

[7] COMPOUNDS WITH BORON AT THE BRIDGEHEAD - A STUDY OF THE STERIC CONSEQUENCES OF PLANAR BORON [J].

BROWN, HC ;

FLETCHER, EA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1951, 73 (06) :2808-2813

[8] Acid-base studies in gaseous systems II The anomalous base strength of the methylamines, a new manifestation of steric strain [J].

Brown, HC ;

Bartholomay, H ;

Taylor, MD .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1944, 66 :435-442

[9] CHIRAL SYNTHESIS VIA ORGANOBORANES .9. CRYSTALLINE CHELATES FROM BORINIC AND BORONIC ESTERS - A SIMPLE PROCEDURE FOR UPGRADING BORINATES AND BORONATES TO MATERIALS APPROACHING 100-PERCENT OPTICAL PURITY [J].

BROWN, HC ;

PRASAD, JVNV .

JOURNAL OF ORGANIC CHEMISTRY, 1986, 51 (24) :4526-4530

[10] CHIRAL SYNTHESIS VIA ORGANOBORANES .6. HYDROBORATION .74. ASYMMETRIC HYDROBORATION OF REPRESENTATIVE HETEROCYCLIC OLEFINS WITH DIISOPINOCAMPHEYLBORANE - SYNTHESIS OF HETEROCYCLIC BORONATES AND HETEROCYCLIC ALCOHOLS OF VERY HIGH ENANTIOMERIC PURITY [J].

BROWN, HC ;

PRASAD, JVNV .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (08) :2049-2054

← 1 2 3 4 5 6 →