A new [2+2] photodimerization of 5-chloro- and 5-methyl-2-pyridone in their inclusion complexes with 1,1′-biphenyl-2,2′-dicarboxylic acid as a model for DNA damage by photodimerization of its thymine component

被引:16
作者
Hirano, S [1 ]
Toyota, S [1 ]
Toda, F [1 ]
机构
[1] Okayama Univ Sci, Fac Sci, Dept Chem, Okayama 7000005, Japan
关键词
D O I
10.1039/b414134b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
As a model for DNA damage by photodimerization of its thymine component, a new [ 2 + 2] photodimerization of 5-chloro and 5-methyl-2-pyridone to the corresponding cis-anti-dimers as their inclusion complexes with 1,1'-biphenyl-2,2'-dicarboxylic acid was found, and the mechanism of this stereoselective solid state reaction was studied by X-ray analysis.
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页码:643 / 644
页数:2
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