Aggregation of hydrocarbons in dilute aqueous solutions

被引：27

作者：

Liu, HQ ^{[1
]}

Ruckenstein, E ^{[1
]}

机构：

[1] SUNY Buffalo, Dept Chem Engn, Amherst, NY 14260 USA

来源：

JOURNAL OF PHYSICAL CHEMISTRY B | 1998年 / 102卷 / 06期

关键词：

D O I：

10.1021/jp972793q

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

On the basis of the fluctuation theory of Kirkwood and Buff, the aggregation number of hydrocarbons in water at infinite dilution, defined on the basis of the radial distribution function, is related to the activity coefficient and partial molar volume of the solute. One concludes that the aggregation number should pass through a maximum with increasing temperature. The effect of pressure on aggregation in dilute solutions is also examined.

引用

页码：1005 / 1012

页数：8

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