Hydrotalcite conversion coating on Mg alloy and its corrosion resistance

被引:109
作者
Wang, Jun [1 ,2 ]
Li, Dandan [1 ]
Yu, Xiang
Jing, Xiaoyan [1 ]
Zhang, Milin [1 ]
Jiang, Zhaohua [2 ]
机构
[1] Harbin Engn Univ, Coll Mat Sci & Chem Engn, Harbin 150001, Peoples R China
[2] Harbin Inst Technol, Coll Chem Engn, Harbin 150001, Peoples R China
关键词
Mg-Al LDH film; Conversion coating; Mg alloy; Corrosion resistance; NI-P; MAGNESIUM ALLOY; THIN-FILMS; BEHAVIOR; SURFACE; AZ91; PRECIPITATION; DEPOSITION; MECHANISM; ALUMINUM;
D O I
10.1016/j.jallcom.2010.01.007
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A magnesium-aluminum layered double hydroxide (Mg-Al LDH) film was fabricated on a Mg alloy substrate by a hydrothermal crystallization method, based on an interface reaction between hydrotalcite slurry and Mg alloy. Magnesium-aluminum layered double hydroxide with carbonate intercalation was obtained by synthesis involving separate nucleation and aging steps, where the Mg-Al LDH film was formed in the aging process. The LDH film was uniform and compact. The film was characterized by XRD, SEM, EDS techniques to study the structure, phase purity and morphology, respectively. Polarization measurements and electrochemical impedance spectroscopy (EIS) showed that the LDH film could effectively protect Mg alloy from corrosion. The cross cutting showed that the adhesion between the film and the substrate was very strong which enhances its potential for practical application. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码:271 / 274
页数:4
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