Organometallic alkane CH activation

被引：417

作者：

Crabtree, RH ^{[1
]}

机构：

[1] Yale Univ, Dept Chem, New Haven, CT 06520 USA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2004年 / 689卷 / 24期

关键词：

alkane functionalization; oxidative addition; sigma bond metathesis;

D O I：

10.1016/j.jorganchem.2004.07.034

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title topic is reviewed with emphasis on catalysis and on recent advances. Alkane sigma complexes, Shilov chemistry and oxidative addition routes are covered. Attention is also given to sigma bond metathesis, surface-bound organometallics and CH activation involving carbene complexes. Closely related reactions of non-alkane substrates such as the Murai reaction are also discussed. (C) 2004 Elsevier B.V.. All rights reserved.

引用

页码：4083 / 4091

页数：9

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