Synthesis of a criss-cross overlapped tetrathiafulvalenophane and a topologically new [2]catenane

被引：30

作者：

Nielsen, MB

Thorup, N

Becher, J

机构：

[1] Odense Univ, Dept Chem, DK-5230 Odense M, Denmark

[2] Tech Univ Denmark, Dept Chem, DK-2800 Lyngby, Denmark

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1998年 / 07期

关键词：

D O I：

10.1039/a707854d

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Using stepwise cyclization reactions followed by an intramolecular coupling, the criss-cross overlapped tetrathiafulvalenophane 8 was readily prepared. The structure of the cis,cis isomer was elucidated by X-ray crystallography which revealed a host-guest complex with chloroform. This electron donor was used for the synthesis of a topologically new type of [2]catenane 11-4PF(6), under ultra-high pressure (10 kbar).

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页码：1305 / 1308

页数：4

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