Direct liquid-phase sulfonation of methane to methanesulfonic acid by SO3 in the presence of a metal peroxide

被引：36

作者：

Mukhopadhyay, S ^{[1
]}

Bell, AT ^{[1
]}

机构：

[1] Univ Calif Berkeley, Dept Chem Engn, Berkeley, CA 94720 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 09期

关键词：

D O I：

10.1002/anie.200390260

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Activation of methane by metal peroxides: Calcium peroxide serves as an effective radical initiator in the liquid-phase sulfonation of methane to methansulfonic acid (MSA) by SO3 [Eq. (1)]. Under the best reaction conditions a 91% conversion of SO3 to MSA was achieved.

引用

页码：1019 / +

页数：4

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