Upgrading of liquid fuel from the pyrolysis of biomass

被引:229
作者
Zhang, SP [1 ]
Yan, YJ [1 ]
Li, TC [1 ]
Ren, ZW [1 ]
机构
[1] E China Univ Sci & Technol, Dept Chem Engn Energy Resources, Shanghai 200237, Peoples R China
关键词
upgrading; biomass; bio-oil;
D O I
10.1016/j.biortech.2004.06.015
中图分类号
S2 [农业工程];
学科分类号
0828 ;
摘要
Pyrolysis of biomass was carried out in a fluidized bed unit (5 kg/h) with the objective of maximizing liquid yield. Liquid product formed in pyrolysis was separated into two phases: water phase and oil phase. The oil phase was upgraded by sulfided Co-Mo-P catalyst in an autoclave. Effects of reaction conditions on the product distribution were investigated, and optimal conditions were therefore concluded. Comparison was made by analysis between the raw oil phase and the upgraded liquid fuel. The significant difference between the raw pyrolytic oil and the upgraded oil was that the former was methanol-soluble while the latter was oil-soluble. (C) 2004 Elsevier Ltd. All rights reserved.
引用
收藏
页码:545 / 550
页数:6
相关论文
共 12 条
[1]   PRODUCTION OF HYDROCARBONS BY CATALYTIC UPGRADING OF A FAST PYROLYSIS BIO-OIL .1. CONVERSION OVER VARIOUS CATALYSTS [J].
ADJAYE, JD ;
BAKHSHI, NN .
FUEL PROCESSING TECHNOLOGY, 1995, 45 (03) :161-183
[2]   PRODUCTION OF HYDROCARBONS BY CATALYTIC UPGRADING OF A FAST PYROLYSIS BIO-OIL .2. COMPARATIVE CATALYST PERFORMANCE AND REACTION PATHWAYS [J].
ADJAYE, JD ;
BAKHSHI, NN .
FUEL PROCESSING TECHNOLOGY, 1995, 45 (03) :185-202
[3]  
[Anonymous], ACS DIV FUEL CHEM PR
[4]   DEVELOPMENTS IN DIRECT THERMOCHEMICAL LIQUEFACTION OF BIOMASS - 1983-1990 [J].
ELLIOTT, DC ;
BECKMAN, D ;
BRIDGWATER, AV ;
DIEBOLD, JP ;
GEVERT, SB ;
SOLANTAUSTA, Y .
ENERGY & FUELS, 1991, 5 (03) :399-410
[5]   Energy production from biomass (part 1): overview of biomass [J].
McKendry, P .
BIORESOURCE TECHNOLOGY, 2002, 83 (01) :37-46
[6]   CONVERSION OF LIGNINS TO HYDROCARBON FUELS [J].
PISKORZ, J ;
MAJERSKI, P ;
RADLEIN, D ;
SCOTT, DS .
ENERGY & FUELS, 1989, 3 (06) :723-726
[7]   THE CONTINUOUS FLASH PYROLYSIS OF BIOMASS [J].
SCOTT, DS ;
PISKORZ, J .
CANADIAN JOURNAL OF CHEMICAL ENGINEERING, 1984, 62 (03) :404-412
[8]   KINETIC-STUDIES OF UPGRADING PINE PYROLYTIC OIL BY HYDROTREATMENT [J].
SHEU, YHE ;
ANTHONY, RG ;
SOLTES, EJ .
FUEL PROCESSING TECHNOLOGY, 1988, 19 (01) :31-50
[9]   Catalytic upgrading of pyrolytic oils to fuel over different zeolites [J].
Vitolo, S ;
Seggiani, M ;
Frediani, P ;
Ambrosini, G ;
Politi, L .
FUEL, 1999, 78 (10) :1147-1159
[10]   Pyrolysis of biomass in the rotating cone reactor: Modelling and experimental justification [J].
Wagenaar, B. M. ;
Prins, W. ;
Van Swaaij, W. P. M. .
CHEMICAL ENGINEERING SCIENCE, 1994, 49 (24B) :5109-5126