Insights into the elimination of HCHO from the clusters [Mn(CO)m(COOMe)]- (Mn = Ru6C, m = 16; Mn = Rh6, m = 15) provided by electrospray mass spectrometry

被引：18

作者：

Dyson, PJ ^{[1
]}

Feeder, N

Johnson, BFG

McIndoe, JS

Langridge-Smith, PRR

机构：

[1] Univ York, Dept Chem, York YO10 5DD, N Yorkshire, England

[2] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England

[3] Univ Edinburgh, Dept Chem, Edinburgh EH9 3JJ, Midlothian, Scotland

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2000年 / 12期

关键词：

D O I：

10.1039/b002978p

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Loss of formaldehyde in the electrospray ionisation fragmentation process of methoxylated hexanuclear carbonyl clusters can be correlated to their macroscopic chemical properties.

引用

页码：1813 / 1815

页数：3

共 21 条

[1] [RU6C(CO)17] - A CASE OF ORGANOMETALLIC CRYSTAL POLYMORPHISM [J].

BRAGA, D ;

GREPIONI, F ;

DYSON, PJ ;

JOHNSON, BFG ;

FREDIANI, P ;

BIANCHI, M ;

PIACENTI, F .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1992, (17) :2565-2571

[2] HEXARUTHENIUM CARBIDO CARBONYL METHYL CLUSTER [PPN][RU6C(CO)16(CH3)] AS CATALYST PRECURSOR FOR HYDROGENATION OF OLEFINS - SYNTHESES AND STRUCTURES OF UNSATURATED AND SATURATED HEXARUTHENIUM HYDRIDO CLUSTERS [PPN][RU6C(CO)15H] AND [PPN][RU6C(CO)16H] [J].

CHIHARA, T ;

YAMAZAKI, H .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1994, 473 (1-2) :273-284

[3] In situ infrared spectroelectrochemical studies of [Ru6C(CO)17] and [Ru6C(CO)16]2-:: the redox induced conversion of carbon monoxide to carbon dioxide [J].

Clark, RJH ;

Dyson, PJ ;

Humphrey, DG ;

Johnson, BFG .

POLYHEDRON, 1998, 17 (17) :2985-2991

[4] REDOX ACTIVATION OF THE HEXANUCLEAR RUTHENIUM CLUSTER [RU6C(CO)16]2- USING OXIDATIVE ADDITION [J].

DRAKE, SR ;

JOHNSON, BFG ;

LEWIS, J .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1989, (02) :243-246

[5]

Dyson PJ, 2000, RAPID COMMUN MASS SP, V14, P311, DOI 10.1002/(SICI)1097-0231(20000315)14:5<311::AID-RCM824>3.0.CO

[6]

2-H

[7]

Dyson PJ, 1999, ADV ORGANOMET CHEM, V43, P43

[8] CHEMISTRY OF IRIDIUM CARBONYL CLUSTERS - SYNTHESIS AND CHEMICAL CHARACTERIZATION OF THE HEXANUCLEAR ANIONS [IR6(CO)15(CO2ME)]-, [IR6(CO)15(CO2ET)] AND [IR6(CO)14(CO2ME))2]2- - CRYSTAL AND MOLECULAR-STRUCTURE OF [N(PPH3)2][IR6(MU-CO)4(CO)11(CO2ME)] [J].

GARLASCHELLI, L ;

MALATESTA, MC ;

MARTINENGO, S ;

DEMARTIN, F ;

MANASSERO, M ;

SANSONI, M .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1986, (04) :777-782

[9] CHEMISTRY OF IRIDIUM CARBONYL .1. CHEMICAL AND STRUCTURAL CHARACTERIZATION OF THE TETRANUCLEAR ANIONS [IR4(MU-CO)3(CO)8(COOR)]- [J].

GARLASCHELLI, L ;

MARTINENGO, S ;

CHINI, P ;

CANZIANI, F ;

BAU, R .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1981, 213 (01) :379-388

[10]

GIANI G, 1981, J ORGANOMET CHEM, V213, pC37

← 1 2 3 →