A novel left-handed double helicate constructed from L-tartrate bridged molybdenum(VI) and gadolinium(III) atoms

被引：97

作者：

Chuan-De, W ^{[1
]}

Lu, CZ ^{[1
]}

Lin, X ^{[1
]}

Wu, DM ^{[1
]}

Lu, SF ^{[1
]}

Zhuang, HH ^{[1
]}

Huang, JS ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 11期

关键词：

D O I：

10.1039/b301542d

中图分类号：

O6 [化学];

学科分类号：

0703 [化学];

摘要：

The one-dimensional double helicate, [NH4][Mo2O4Gd( H2O)(6)(L-C4H2O6)(2)] . 4H(2)O (1), which was synthesized by the reaction of GdCl3, L-tartaric acid and ammonium molybdate in acidified water solution, is built up by two heft-handed single-helical chains, linked up further by eight-coordinated Gd-III pieces in an enantiopure left-handed double helical configuration, of which each helix is formed by L-tartrate bridged six-coordinated Mo-VI atoms.

引用

页码：1284 / 1285

页数：2

共 40 条

[1]

Let's twist again - Double-stranded, triple-stranded, and circular helicates [J].