Heterogeneous asymmetric catalytic aminohydroxylation promoted by a bis-Cinchona alkaloid derivative supported onto an insoluble organic polymeric matrix

被引：26

作者：

Mandoli, A ^{[1
]}

Pini, D ^{[1
]}

Agostini, A ^{[1
]}

Salvadori, P ^{[1
]}

机构：

[1] CNR, Ctr Studio Macromol Stereordinate Otticamente Att, Dipartimento Chim & Chim Ind, I-56126 Pisa, Italy

来源：

TETRAHEDRON-ASYMMETRY | 2000年 / 11卷 / 20期

关键词：

D O I：

10.1016/S0957-4166(00)00399-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

By using a bis(quinidinyl)phthalazine derivative linked to an insoluble organic polymer, 87% e.e. was obtained in the osmium-mediated catalytic heterogeneous asymmetric aminohydroxylation of isopropyl trans-cinnamate. The recycling of the polymeric ligand-osmium complex was also investigated. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：4039 / 4042

页数：4

共 8 条

[1] UNPRECEDENTED REACTIVITY AND SELECTIVITY IN HETEROGENEOUS ASYMMETRIC CATALYTIC DIHYDROXYLATION OF ALKENES [J].