Molecular recognition. Electrostatic effects in supramolecular self-assembly

被引：35

作者：

Crowley, JD ^{[1
]}

Goshe, AJ ^{[1
]}

Bosnich, B ^{[1
]}

机构：

[1] Univ Chicago, Dept Chem, Chicago, IL 60637 USA

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 03期

关键词：

D O I：

10.1039/b210957c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A di-positively charged metal-based receptor is shown to form 1:1 or 2:1 association complexes with rigid, linear two-site guests depending on the site separation, suggesting that electrostatic repulsion controls the association nuclearity.

引用

页码：392 / 393

页数：2

共 26 条

[1] The rational design of high symmetry coordination clusters [J].

Caulder, DL ;

Raymond, KN .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1999, (08) :1185-1200

[2]

Connors K. A., 1987, BINDING CONSTANTS, P50

[3] Self-assembly of [2]catenanes containing metals in their backbones [J].

Fujita, M .

ACCOUNTS OF CHEMICAL RESEARCH, 1999, 32 (01) :53-61

[4] Spontaneous assembly of ten components into two interlocked, identical coordination cages [J].

Fujita, M ;

Fujita, N ;

Ogura, K ;

Yamaguchi, K .

NATURE, 1999, 400 (6739) :52-55

[5] Metal-directed self-assembly of two- and three-dimensional synthetic receptors [J].

Fujita, M .

CHEMICAL SOCIETY REVIEWS, 1998, 27 (06) :417-425

[6] Molecular paneling via coordination [J].

Fujita, M ;

Umemoto, K ;

Yoshizawa, M ;

Fujita, N ;

Kusukawa, T ;

Biradha, K .

CHEMICAL COMMUNICATIONS, 2001, (06) :509-518

[7]

Goshe AJ, 2001, HELV CHIM ACTA, V84, P2971, DOI 10.1002/1522-2675(20011017)84:10<2971::AID-HLCA2971>3.0.CO

[8]

2-M

[9] Supramolecular recognition. Terpyridyl palladium and platinum molecular clefts and their association with planar platinum complexes [J].

Goshe, AJ ;

Steele, IM ;

Bosnich, B .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (02) :444-451

[10] Supramolecular recognition: On the kinetic lability of thermodynamically stable host-guest association complexes [J].

Goshe, AJ ;

Steele, IM ;

Ceccarelli, C ;

Rheingold, AL ;

Bosnich, B .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2002, 99 (08) :4823-4829

← 1 2 3 →