Ureidotriazine-based supramolecular copolymers

被引:37
作者
Hirschberg, JHKK
Ramzi, A
Sijbesma, RP
Meijer, EW
机构
[1] Eindhoven Univ Technol, Lab Macromol & Organ Chem, NL-5600 MB Eindhoven, Netherlands
[2] Dutch Polymer Inst, NL-5600 MB Eindhoven, Netherlands
关键词
D O I
10.1021/ma025723c
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
A study was performed on ureidotriazine-based supramolecular copolymers consisting of rigid-rod-like and coil-like segments. The rigid-rod-like segments were formed by monomers, while the random coils were formed by poly(ethylene/butylene) that were functionalized with either one or two ureidotriazine units. It was found that in bulk, phase separation between components results in a fibrillar morphology which coarsens upon annealing.
引用
收藏
页码:1429 / 1432
页数:4
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