Electrical and magnetic properties of titanium diselenide intercalated with cobalt

被引:23
作者
Pleshchev, VG
Titov, AN
Kuranov, AV
机构
[1] Ural State University
关键词
Spectroscopy; Titanium; Experimental Study; Cobalt; Electrical Conductivity;
D O I
10.1134/1.1130094
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
This paper discusses experimental studies of the temperature dependence of the magnetic susceptibility, electrical conductivity, and Seebeck coefficient of the compounds CoxTiSe2 (0.1 less than or equal to x less than or equal to 0.5), along with the structural behavior exhibited by these compounds. For Co0.5TiSe2, the observed temperature dependence of the magnetic susceptibility is characteristic of an antiferromagnet with a Neel temperature of 510 K. The data obtained on the structural characteristics and physical properties of the intercalated phases are interpreted using a model that assumes the formation of bands of localized states near the Fermi level. (C) 1997 American Institute of Physics.
引用
收藏
页码:1442 / 1445
页数:4
相关论文
共 20 条
[1]  
Anselm A. I., 1978, INTRO SEMICONDUCTOR
[2]  
Antropov V. M., 1996, Physics of the Solid State, V38, P713
[3]  
Arnaud Y., 1976, J SOLID STATE CHEM, V17, P9
[4]   TITANIUM DITELLURIDE - BAND-STRUCTURE, PHOTOEMISSION, AND ELECTRICAL AND MAGNETIC-PROPERTIES [J].
DEBOER, DKG ;
VANBRUGGEN, CF ;
BUS, GW ;
COEHOORN, R ;
HAAS, C ;
SAWATZKY, GA ;
MYRON, HW ;
NORMAN, D ;
PADMORE, H .
PHYSICAL REVIEW B, 1984, 29 (12) :6797-6809
[5]  
FIRSOV YA, 1975, POLARONS COLLECTION
[6]   ELECTRONIC-PROPERTIES OF INTERCALATION COMPLEXES OF THE TRANSITION-METAL DICHALCOGENIDES [J].
FRIEND, RH ;
YOFFE, AD .
ADVANCES IN PHYSICS, 1987, 36 (01) :1-94
[7]  
Hibma T., 1982, Intercalation Chemistry
[8]  
HUNTLEY DR, 1974, J SOLID STATE CHEM, V52, P233
[9]  
KALINNIKOV VT, 1980, INTRO MAGNETOCHEMIST
[10]   TRANSPORT AND RAMAN STUDIES OF THE GROUP-IV LAYERED COMPOUNDS AND THEIR LITHIUM INTERCALATES - LIXTIS2, LIXTISE2, LIXZRS2, LIXZRSE2, LIXHFS2 AND LIXHFSE2 [J].
KLIPSTEIN, PC ;
PEREIRA, CM ;
FRIEND, RH .
PHILOSOPHICAL MAGAZINE B-PHYSICS OF CONDENSED MATTER STATISTICAL MECHANICS ELECTRONIC OPTICAL AND MAGNETIC PROPERTIES, 1987, 56 (05) :531-559