Determination of glyphosate mono-isopropylamine salt in process samples using flow injection analysis with tris(2,2′-bipyridyl)ruthenium(II) chemiluminescence detection

被引：18

作者：

Adcock, JL

Barnett, NW

Gerardi, RD

Lenehan, CE

Lewis, SW ^{[1
]}

机构：

[1] Deakin Univ, Sch Biol & Chem Sci, Ctr Chiral & Mol Technol, Geelong, Vic 3217, Australia

[2] Nufarm Ltd, Laverton N, Vic 3026, Australia

来源：

TALANTA | 2004年 / 64卷 / 02期

关键词：

D O I：

10.1016/j.talanta.2004.03.024

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The mono-isopropylamine salt of glyphosate was selectively determined directly in industrial and commercial formulations using flow injection analysis with tris(2,2'-bipyridyl)ruthenium(II) chemiluminescence detection without the need for separation. Glyphosate and its mono-isopropylamine salt furnished detection limits of 7x10(-9) and 3.5x10(-10) M and relative standard deviations of 0.4% at 1x10(-7) M and 0.8% at 5x10(-8) M, respectively. The methodology is robust and reliable with samples subjected only to aqueous dilution prior to analysis. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：534 / 537

页数：4

共 13 条

[1] DETERMINATION OF MORPHINE IN-PROCESS STREAMS USING FLOW-INJECTION ANALYSIS WITH CHEMILUMINESCENCE DETECTION [J].