Mercuric triflate catalyzed hydroxylative carbocyclization of 1,6-enynes

被引：67

作者：

Nishizawa, M ^{[1
]}

Yadav, VK ^{[1
]}

Skwarczynski, M ^{[1
]}

Takao, H ^{[1
]}

Imagawa, H ^{[1
]}

Sugihara, T ^{[1
]}

机构：

[1] Tokushima Bunri Univ, Fac Pharmaceut Sci, Tokushima 7708514, Japan

来源：

ORGANIC LETTERS | 2003年 / 5卷 / 10期

关键词：

D O I：

10.1021/ol034201u

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] Hg(OTf)(2) exhibits remarkable catalytic activity for the hydroxylative cyclization of 1,6-enynes. The present procedure should involve a sequence of mercuration of a terminal alkyne, carbocyclization, hydration, and protodemercuration that regenerates the catalyst.

引用

页码：1609 / 1611

页数：3

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