[H2C=ZrH2]:: The simplest carbene hydride complex, agostic bonding, and C-H activation of CH4 to form [(CH3)2ZrH2]

被引:35
作者
Andrews, L [1 ]
Cho, HG [1 ]
Wang, XF [1 ]
机构
[1] Univ Virginia, Dept Chem, Charlottesville, VA 22904 USA
关键词
agostic interactions; C-H activation; density functional calculations; IR spectroscopy; matrix isolation;
D O I
10.1002/anie.200461526
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
[No abstract available]
引用
收藏
页码:113 / 116
页数:4
相关论文
共 22 条
[1]   Infrared spectra and density functional theory calculations on transition metal nitrosyls. Vibrational frequencies of unsaturated transition metal nitrosyls [J].
Andrews, L ;
Citra, A .
CHEMICAL REVIEWS, 2002, 102 (04) :885-911
[2]   MECHANISMS FOR THE REACTIONS BETWEEN METHANE AND THE NEUTRAL TRANSITION-METAL ATOMS FROM YTTRIUM TO PALLADIUM [J].
BLOMBERG, MRA ;
SIEGBAHN, PEM ;
SVENSSON, M .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (15) :6095-6102
[3]   Homogeneous metathesis polymerization by well-defined group VI and group VIII transition-metal alkylidenes: Fundamentals and applications in the preparation of advanced materials [J].
Buchmeiser, MR .
CHEMICAL REVIEWS, 2000, 100 (04) :1565-1604
[4]   The prediction of vibrational frequencies of inorganic molecules using density functional theory [J].
Bytheway, I ;
Wong, MW .
CHEMICAL PHYSICS LETTERS, 1998, 282 (3-4) :219-226
[5]   REACTIONS OF LASER-ABLATED TITANIUM, ZIRCONIUM, AND HAFNIUM ATOMS WITH OXYGEN MOLECULES IN CONDENSING ARGON [J].
CHERTIHIN, GV ;
ANDREWS, L .
JOURNAL OF PHYSICAL CHEMISTRY, 1995, 99 (17) :6356-6366
[6]   REACTIONS OF LASER-ABLATED ZR AND HF ATOMS WITH HYDROGEN - MATRIX INFRARED-SPECTRA OF THE MH, MH(2), MH(3), AND MH(4) MOLECULES [J].
CHERTIHIN, GV ;
ANDREWS, L .
JOURNAL OF PHYSICAL CHEMISTRY, 1995, 99 (41) :15004-15010
[7]   Formation of a simple hafnium methylidene complex by reaction of methyl fluoride with laser-ablated hafnium atoms [J].
Cho, HG ;
Andrews, L .
ORGANOMETALLICS, 2004, 23 (19) :4357-4361
[8]   Persistent photo-reversible transition-metal methylidene system generated from reaction of methyl fluoride with laser-ablated zirconium atoms and isolated in a solid argon matrix [J].
Cho, HG ;
Andrews, L .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (33) :10485-10492
[9]   Photoreversible hydrogen migration system in a solid argon matrix formed by the reaction of methyl fluoride with laser-ablated titanium atoms [J].
Cho, HG ;
Andrews, L .
JOURNAL OF PHYSICAL CHEMISTRY A, 2004, 108 (30) :6294-6301
[10]   THE ORGANOMETALLIC CHEMISTRY OF ALKANES [J].
CRABTREE, RH .
CHEMICAL REVIEWS, 1985, 85 (04) :245-269