Zinc stannate (Zn2SnO4) dye-sensitized solar cells

被引:361
作者
Tan, Bing [1 ]
Toman, Elizabeth [1 ]
Li, Yanguang [1 ]
Wu, Yiying [1 ]
机构
[1] Ohio State Univ, Dept Chem, Columbus, OH 43210 USA
关键词
D O I
10.1021/ja070804f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Developing new electrode materials is important for high-performance dye-sensitized solar cells (DSSCs). Previous research has mostly been limited to simple binary oxides. The application of multication oxides in DSSC has been rarely explored. In this communication, we report the promising application of Zn2SnO4 nanoparticles in DSSC. An overall light-to-electricity efficiency as high as 3.8% has been achieved under 1 sun AM 1.5 illumination. In comparison with ZnO and SnO2 as its simple component oxides, a Zn2SnO4 cell is more stable against acidic dyes than a ZnO cell, while it has much better performance than a SnO2 cell. Our results suggest that multication oxides, with the availability of a wide range of compositions and tunable properties, hold great promise as new electrode materials for DSSCs.
引用
收藏
页码:4162 / +
页数:3
相关论文
共 21 条
[1]   Nanocrystalline mesoporous strontium titanate as photoelectrode material for photosensitized solar devices:: Increasing photovoltage through flatband potential engineering [J].
Burnside, S ;
Moser, JE ;
Brooks, K ;
Grätzel, M ;
Cahen, D .
JOURNAL OF PHYSICAL CHEMISTRY B, 1999, 103 (43) :9328-9332
[2]   Dye-sensitized solar cells with conversion efficiency of 11.1% [J].
Chiba, Yasuo ;
Islam, Ashraful ;
Watanabe, Yuki ;
Komiya, Ryoichi ;
Koide, Naoki ;
Han, Liyuan .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS & EXPRESS LETTERS, 2006, 45 (24-28) :L638-L640
[3]   Hierarchically mesostructured doped CeO2 with potential for solar-cell use [J].
Corma, A ;
Atienzar, P ;
García, H ;
Chane-Ching, JY .
NATURE MATERIALS, 2004, 3 (06) :394-397
[4]   Search for improved transparent conducting oxides:: A fundamental investigation of CdO, Cd2SnO4, and Zn2SnO4 [J].
Coutts, TJ ;
Young, DL ;
Li, X ;
Mulligan, WP ;
Wu, X .
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A-VACUUM SURFACES AND FILMS, 2000, 18 (06) :2646-2660
[5]   Conversion of sunlight to electric power by nanocrystalline dye-sensitized solar cells [J].
Grätzel, M .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2004, 164 (1-3) :3-14
[6]   RU(II) sensitized Nb2O5 solar cell made by the sol-gel process [J].
Guo, P ;
Aegerter, MA .
THIN SOLID FILMS, 1999, 351 (1-2) :290-294
[7]   Highly efficient photon-to-electron conversion with mercurochrome-sensitized nanoporous oxide semiconductor solar cells [J].
Hara, K ;
Horiguchi, T ;
Kinoshita, T ;
Sayama, K ;
Sugihara, H ;
Arakawa, H .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2000, 64 (02) :115-134
[8]   Enhanced photoelectrochemical performance of ZnO electrodes sensitized with N-719 [J].
Kakiuchi, K ;
Hosono, E ;
Fujihara, S .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2006, 179 (1-2) :81-86
[9]   Dye-sensitized core-shell nanocrystals:: Improved efficiency of mesoporous tin oxide electrodes coated with a thin layer of an insulating oxide [J].
Kay, A ;
Grätzel, M .
CHEMISTRY OF MATERIALS, 2002, 14 (07) :2930-2935
[10]   Studies of the adsorption process of Ru complexes in nanoporous ZnO electrodes [J].
Keis, K ;
Lindgren, J ;
Lindquist, SE ;
Hagfeldt, A .
LANGMUIR, 2000, 16 (10) :4688-4694