Kinetics of formation of vesicles from lecithin/sodium xylenesulfonate micelles from stopped-flow measurements

被引:29
作者
Campbell, SE [1 ]
Zhang, ZQ [1 ]
Friberg, SE [1 ]
Patel, R [1 ]
机构
[1] Clarkson Univ, Dept Chem, Potsdam, NY 13699 USA
关键词
D O I
10.1021/la9707742
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The kinetics of vesicle formation from hydrotrope/lecithin micelles in the system of lecithin, sodium xylenesulfonate (SXS), and water were studied via the stopped-flow process in conjunction with light scattering; The essential phases in the system are a micellar (L-1) phase and a lamellar liquid-crystalline (LLC) phase. Based upon light scattering and conductance measurements in the L-1 phase, the ratio of SXS to lecithin molecules in the micelles was approximately 1. The results of the stopped-flow process showed the mechanism of formation for the vesicles, which lie in equilibrium between the L-1 and LLC phases, to be by the agglomeration of fragments.
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收藏
页码:590 / 594
页数:5
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