Functionalization of multiwalled carbon nanotubes by reversible addition fragmentation chain-transfer polymerization

被引：129

作者：

Cui, J ^{[1
]}

Wang, WP ^{[1
]}

You, YZ ^{[1
]}

Liu, CH ^{[1
]}

Wang, PH ^{[1
]}

机构：

[1] Hefei Univ Technol, Dept Polymer Sci & Engn, Hefei 230009, Anhui, Peoples R China

来源：

POLYMER | 2004年 / 45卷 / 26期

关键词：

carbon nanotube; RAFT;

D O I：

10.1016/j.polymer.2004.10.068

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

In this study, a new way was used to chemically synthesize polymer-connected MWNT nanocomposites. Reversible addition fragmentation chain-transfer (RAFT) agent was successfully grafted onto the surface of multiwalled carbon nanotubes (MWNTs). Polystyrene (PS) chains were successfully grafted from the surface of MWNTs via RAFT process by using RAFr agent immobilized on MWNTs. FTIR, XPS and TGA were used to determine chemical structure and the grafted PS quantities of the resulting products. TEM images of the samples provide direct evidence for the formation of a core-shell nanostructure, i.e. the MWNT coated with polymer layer and the solubility be improved. (C) 2004 Elsevier Ltd. All rights reserved.

引用

页码：8717 / 8721

页数：5

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