Effect of micro-sized SiO2-particle on the performance of PVDF blend membranes via TIPS

被引：156

作者：

Cui, Aihua ^{[1
]}

Liu, Zhen ^{[1
]}

Xiao, Changfa ^{[1
]}

Zhang, Yufeng ^{[1
]}

机构：

[1] Tianjin Polytech Univ, Minist Educ, Key Lab Hollow Fiber Membrane Mat & Membrane Proc, Tianjin 300160, Peoples R China

来源：

JOURNAL OF MEMBRANE SCIENCE | 2010年 / 360卷 / 1-2期

关键词：

Poly (vinylidene fluoride) (PVDF); Thermally induced phase separation (TIPS); Silica (SiO2); Blend membrane; INDUCED PHASE-SEPARATION; HOLLOW-FIBER MEMBRANE; POLYVINYLIDENE FLUORIDE; MORPHOLOGY; BEHAVIOR;

D O I：

10.1016/j.memsci.2010.05.023

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Poly (vinylidene fluoride) blend membranes were prepared by melt-blending the ternary mixture of PVDF/SiO2/dibutyl phthalate (DBP) in combination of thermally induced phase separation (TIPS). The results of water permeability and instrumental analysis illustrated that micro-size SiO2 and DBP concentration obviously affected the performance and structure of the PVDF membranes. It was found that water flux effect and tensile strength increased with micro-particle content, but it reached limit content above which water flux did not increase. The surface and cross-section of the membranes were characterized by AFM and SEM depended on SiO2 weight fraction. The results showed that the morphology of PVDF and the formation of the spherulitic morphology can be disturbed by SiO2. Porosity and the water flux of the blend membrane increased, the membrane strength decreased with increasing DBP concentration. (C) 2010 Elsevier B.V. All rights reserved.

引用

页码：259 / 264

页数：6

共 27 条

[1] Effect of TiO2 nanoparticles on fouling mitigation of ultrafiltration membranes for activated sludge filtration [J].

Bae, TH ;

Tak, TM .

JOURNAL OF MEMBRANE SCIENCE, 2005, 249 (1-2) :1-8

[2] Preparation and characterization of novel porous PVDF-ZrO2 composite membranes [J].

Bottino, A ;

Capannelli, G ;

Comite, A .

DESALINATION, 2002, 146 (1-3) :35-40

[3] Preparation and properties of novel organic-inorganic porous membranes [J].

Bottino, A ;

Capannelli, G ;

D'Asti, V ;

Piaggio, P .

SEPARATION AND PURIFICATION TECHNOLOGY, 2001, 22-3 (1-3) :269-275

[4]

Cheng LP, 1999, J POLYM SCI POL PHYS, V37, P2079, DOI 10.1002/(SICI)1099-0488(19990815)37:16<2079::AID-POLB11>3.3.CO

[5]

2-H

[6] Preparation of PVDF/PMMA blend microporous membranes for lithium ion batteries via thermally induced phase separation process [J].

Cui, Zhen-Yu ;

Xu, You-Yi ;

Zhu, Li-Ping ;

Wei, Xiu-Zhen ;

Zhang, Chun-Fang ;

Zhu, Bao-Ku .

MATERIALS LETTERS, 2008, 62 (23) :3809-3811

[7] Influence of alcohol-based nonsolvents on the formation and morphology of PVDF membranes in phase inversion process [J].

Dan-ying Zuo ;

Bao-ku Zhu ;

Jian-hua Cao ;

You-yi Xu .

CHINESE JOURNAL OF POLYMER SCIENCE, 2006, 24 (03) :281-289

[8] Formation of poly(vinylidene fluoride) (PVDF) membranes via thermally induced phase separation [J].

Gu, Minghao ;

Zhang, Jun ;

Wang, Xiaolin ;

Tao, Haijun ;

Ge, Litian .

DESALINATION, 2006, 192 (1-3) :160-167

[9] Preparation of porous PVDF membrane via thermally induced phase separation with diluent mixture of DBP and DEHP [J].

Ji, Gen-Liang ;

Du, Chun-Hui ;

Zhu, Bao-Ku ;

Xu, You-Yi .

JOURNAL OF APPLIED POLYMER SCIENCE, 2007, 105 (03) :1496-1502

[10]

Ke K.C., 2003, POLYM NONIONIC NANOM, P23

← 1 2 3 →