Electrochemical quartz crystal microbalance study for vanadium hexacyanoferrates: monitoring of film growth and ion effects during redox reactions

被引：29

作者：

Wang, Y ^{[1
]}

Zhu, GY ^{[1
]}

Wang, EK ^{[1
]}

机构：

[1] Chinese Acad Sci, Changchun Inst Appl Chem, Electroanalyt Chem Lab, Changchun 130022, Jilin, Peoples R China

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1997年 / 430卷 / 1-2期

基金：

中国国家自然科学基金;

关键词：

vanadium hexacyanoferrates; electrochemical quartz crystal microbalance; film growth; ion effect;

D O I：

10.1016/S0022-0728(97)00104-6

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

An electrochemical quartz crystal microbalance was employed to monitor directly the growth of vanadium hexacyanoferrate (VHF) films on platinum substrates during electrodeposition and interfacial coagulation in the solution containing sulfuric acid electrolyte, vanadium(IV) and hexacyanoferrate(III). Mass changes of the gold/crystal working electrode were correlated with cyclic voltammetry data. Effects of cations (NH4+, Li+, Na+ and K+), anions (SO42- and NO3-) and solvent during redox reactions of the films were studied. The results show that cations were incorporated into the film during reduction and expelled from the film during oxidation. Solvent also participates in VHF electrochemistry, and its role cannot be neglected. Anions play no role in VHF electrochemistry. (C) 1997 Elsevier Science S.A.

引用

页码：127 / 132

页数：6

共 48 条

[1] POLYNUCLEAR NICKEL HEXACYANOFERRATES - MONITORING OF FILM GROWTH AND HYDRATED COUNTER-CATION FLUX STORAGE DURING REDOX REACTIONS [J].