Monohapto-allyl Pd(II) complexes with bidentate hybrid P,N ligands

被引：31

作者：

Braunstein, P

Jing, ZA

Welter, R

机构：

[1] Univ Strasbourg 1, Chim Coordinat Lab, UMR 7513, CNRS, F-67070 Strasbourg, France

[2] Univ Strasbourg 1, Lab DECMET, UMR 7513, CNRS, F-67070 Strasbourg, France

来源：

DALTON TRANSACTIONS | 2003年 / 04期

关键词：

D O I：

10.1039/b212393m

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Using a new oxazoline-phosphonite P,N ligand, we establish that in contrast with commonly held belief, bidentate ligands can lead to unusually stable eta(1)-allyl complexes of Pd(II); CO insertion into their Pd-C sigma-bond affords the corresponding 3-butenoyl complexes under mild conditions.

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收藏

页码：507 / 509

页数：3

相关论文

共 36 条

[1] Ethylene polymerization with half-sandwich allyl imido complexes of tantalum [J].

Antonelli, DM ;

Leins, A ;

Stryker, JM .

ORGANOMETALLICS, 1997, 16 (12) :2500-2502

[2]

Barloy L, 2000, EUR J INORG CHEM, P2523

[3] Heterobimetallic intermediates in alkene insertion reactions into a Pd-acetyl bond [J].

Braunstein, P ;

Durand, J ;

Knorr, M ;

Strohmann, C .

CHEMICAL COMMUNICATIONS, 2001, (02) :211-212

[4] Palladium complexes with a new hemilabile bis(oxazoline)phenylphosphonite ligand.: Characterization of an unprecedented chloro palladium(II)-(η1-allyl) complex [J].

Braunstein, P ;

Naud, F ;

Dedieu, A ;

Rohmer, MM ;

DeCian, A ;

Rettig, SJ .

ORGANOMETALLICS, 2001, 20 (14) :2966-2981

[5]

Braunstein P, 2000, ANGEW CHEM INT EDIT, V39, P2867, DOI 10.1002/1521-3773(20000818)39:16<2867::AID-ANIE2867>3.0.CO

[6]

2-X

[7] ORGANOPALLADIUM(IV) CHEMISTRY - OXIDATIVE ADDITION OF ORGANOHALIDES TO DIMETHYLPALLADIUM(II) COMPLEXES TO FORM ETHYL, SIGMA-BENZYL, AND SIGMA-ALLYLPALLADIUM(IV) COMPLEXES [J].

BYERS, PK ;

CANTY, AJ .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (10) :639-641

[8] ENANTIOSELECTIVE HOMOGENEOUS CATALYSIS INVOLVING TRANSITION-METAL ALLYL INTERMEDIATES [J].

CONSIGLIO, G ;

WAYMOUTH, RM .

CHEMICAL REVIEWS, 1989, 89 (01) :257-276

[9] INFLUENCE OF LIGANDS AND ANIONS ON THE RATE OF CARBON-MONOXIDE INSERTION INTO PALLADIUM METHYL BONDS IN THE COMPLEXES (P-P)PD(CH3)CL AND [(P-P)PD(CH3)(L)]+SO3CF3- (P-P = DPPE, DPPP, DPPB, DPPF, L = CH3CN, PPH3) [J].

DEKKER, GPCM ;

ELSEVIER, CJ ;

VRIEZE, K ;

VANLEEUWEN, PWNM .

ORGANOMETALLICS, 1992, 11 (04) :1598-1603

[10]

ELSCHENBROICH C, 1989, ORGANOMETALLICS, P287

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