Solid-state tin-117 NMR: A powerful tool for the analysis of organotin functionalities anchored to insoluble polymers

被引：23

作者：

Dumartin, G

Kharboutli, J

Delmond, B

Pereyre, M

Biesemans, M

Gielen, M

Willem, R

机构：

[1] FREE UNIV BRUSSELS,HNMR & AOSC,FAC SCI APPL,HIGH RESOLUT NMR CTR,B-1050 BRUSSELS,BELGIUM

[2] FREE UNIV BRUSSELS,HNMR & AOSC,FAC SCI APPL,DEPT GEN & ORGAN CHEM,B-1050 BRUSSELS,BELGIUM

来源：

ORGANOMETALLICS | 1996年 / 15卷 / 01期

关键词：

D O I：

10.1021/om9505930

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Various polymer-supported organotin derivatives of the type P-(CH2)(n)SnBu(2) Sigma (Sigma = H, halogen, Ph) were prepared from insoluble polystyrene, and their reactivity was studied. The solid support used in the present report is Amberlite XE 305 (P). Solid-state tin-117 NMR was successfully used for qualitative and quantitative analysis of the different tin species present in the polymers.

引用

页码：19 / 23

页数：5

共 32 条

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