Self-assembly of chiral hydrogen-bonded grid layers from terephthalic Siamese twins

被引:17
作者
Holy, P
Sehnal, P
Tichy, M
Závada, J
Císarová, I
机构
[1] Acad Sci Czech Republ, Inst Organ Chem & Biochem, CR-16610 Prague 6, Czech Republic
[2] Charles Univ Prague, Dept Inorgan Chem, Fac Nat Sci, CR-12840 Prague 2, Czech Republic
关键词
D O I
10.1016/S0957-4166(02)00758-9
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
2,2',5,5'-Tetracarboxy- and 2,2', 5,5'-tetracarbamoyl-substituted biphenyls and also the 2,2',3,3',6,6'-hexacarboxy-substituted analogue behave as Siamese twins of terephthalic tectons in the single crystal self-assembly, giving rise to chiral 2D grid layers. A comparison has been made with the corresponding 2,2',6,6'-tetrasubstituted biphenyls which mimic isophthalic twins in their self-assembly. (C) 2003 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:245 / 253
页数:9
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