NMR Chemical Shifts of Trace Impurities: Common Laboratory Solvents, Organics, and Gases in Deuterated Solvents Relevant to the Organometallic Chemist

被引：2968

作者：

Fulmer, Gregory R. ^{[1
]}

Miller, Alexander J. M. ^{[2
,3
]}

Sherden, Nathaniel H. ^{[2
,3
]}

Gottlieb, Hugo E. ^{[4
]}

Nudelman, Abraham ^{[4
]}

Stoltz, Brian M. ^{[2
,3
]}

Bercaw, John E. ^{[2
,3
]}

Goldberg, Karen I. ^{[1
]}

机构：

[1] Univ Washington, Dept Chem, Seattle, WA 98195 USA

[2] CALTECH, Arnold & Mabel Beckman Labs Chem Synth, Pasadena, CA 91125 USA

[3] CALTECH, Caltech Ctr Catalysis & Chem Synth, Div Chem & Chem Engn, Pasadena, CA 91125 USA

[4] Bar Ilan Univ, Dept Chem, IL-52900 Ramat Gan, Israel

来源：

ORGANOMETALLICS | 2010年 / 29卷 / 09期

关键词：

Impurities - Chemical shift - Deuterium - Organic solvents - Dichloromethane;

D O I：

10.1021/om100106e

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Tables of H-1 and C-13 NMR chemical shifts have been compiled for common organic compounds often used as reagents or found as products or contaminants in deuterated organic solvents. Building upon the work of Gottlieb, Kotlyar, and Nudelman in the Journal of Organic Chemistry, signals for common impurities are now reported in additional NMR solvents (tetrahydrofuran-d(8), toluene-d(8), dichloromethane-d(2), chlorobenzene-d(5), and 2,2,2-trifluoroethanol-d(3)) which are frequently used in organometallic laboratories. Chemical shifts for other organics which are often used as reagents or internal standards or are found as products in organometallic chemistry are also reported for all the listed solvents.

引用

页码：2176 / 2179

页数：4

共 3 条

[1]

Balci M, 2005, BASIC 1H- AND I3C-NMR SPECTROSCOPY, P1

[2] NMR chemical shifts of common laboratory solvents as trace impurities [J].