Novel synthesis of hybrid calixphyrin macrocycles

被引:70
作者
Bucher, C
Seidel, D
Lynch, V
Král, V
Sessler, JL [1 ]
机构
[1] Univ Texas, Dept Chem & Biochem, Inst Mol & Cellular Biol, Austin, TX 78712 USA
[2] Czech Tech Univ, Dept Analyt Chem, Prague 16610 6, Czech Republic
关键词
D O I
10.1021/ol006316t
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
[GRAPHICS] The reaction of benzaldehyde with excess pyrrole at room temperature in the absence of solvent affords a mixture of meso-substituted polypyrranes species. After separation by column chromatography, these may be used to prepare a range of calix[4]phyrin macrocycles by condensation with acetone under conditions of acid catalysis.
引用
收藏
页码:3103 / 3106
页数:4
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