Dichloro [2,3,5,6-tetra(2-pyridyl)pyrazine]-copper(II), [CuCl2(C24H16N6)]

被引：10

作者：

Kozisek, J

Marek, J

Baloghova, Z

Valigura, D

机构：

[1] Slovak Univ Technol Bratislava, Fac Chem Technol, Dept Inorgan Chem, Bratislava 81237, Slovakia

[2] Masaryk Univ, Fac Sci, Dept Inorgan Chem, Brno 61137, Czech Republic

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1997年 / 53卷

关键词：

D O I：

10.1107/S0108270197011396

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In molecules of [Cu(TPPZ)Cl-2] [TPPZ is 2,3,5,6-tetra(2- pyridyl)pyrazine], the central Cu-II atom has a square-pyramidal coordination environment, defined by three TPPZ N atoms and by two chloro ligands, one of which is apical. The other three TPPZ N atoms remain uncoordinated. The Cu-N distances are in the range 1.975 (2)-2.058 (2) Angstrom and the Cu-Cl bond lengths are 2.214 (1) and 2.465 (1) Angstrom.

引用

页码：1813 / 1815

页数：3

共 7 条

[1] SYNTHESIS, STRUCTURE, AND SPECTROSCOPIC PROPERTIES OF COPPER(II) COMPOUNDS CONTAINING NITROGEN SULFUR DONOR LIGANDS - THE CRYSTAL AND MOLECULAR-STRUCTURE OF AQUA[1,7-BIS(N-METHYLBENZIMIDAZOL-2'-YL)-2,6-DITHIAHEPTANE]COPPER(II) PERCHLORATE [J].