Groundwater mixing dynamics at a Canadian Shield mine

Temporal and spatial variations in geochemistry and isotopes in mine inflows at the Con Mine, Yellowknife, are studied to access the impact of underground openings on deep groundwater flow in the Canadian Shield. Periodic sampling of inflow at 20 sites from 700 to 1615 m depth showed that salinities range from 1.4 to 290 gn, with tritium detected at all depths. Three mixing end-members are identified: (1) Ca(Na)-Cl Shield brine; (2) glacial meltwater recharged at the margin of the retreating Laurentide ice sheet at similar to 10 ka; and (3) modern meteoric water. Mixing fractions, calculated for inflows on five mine levels, illustrate the infiltration of modern water along specific fault planes. Tritium data for the modem component are corrected for mixing with brine and glacial waters and interpreted with an exponential-piston flow model. Results indicate that the mean transit time from surface to 1300 m depth is about 23 years in the early period after drift construction in 1979, but decreases to about 17 years in the past decade. The persistence of glacial meltwater in the subsurface to the present time, and the rapid circulation of modem meteoric water since the start of mining activities underline the importance of gradient, in addition to permeability, as a control on deep groundwater flow in the Canadian Shield. (C) 2000 Elsevier Science B.V. All rights reserved.