Carbon-coated fluorinated graphite for high energy and high power densities primary lithium batteries

被引:106
作者
Zhang, Q. [1 ]
D'Astorg, S. [1 ]
Xiao, P. [2 ]
Zhang, X. [3 ]
Lu, L. [2 ]
机构
[1] Cranfield Univ, Dept Mat, Cranfield MK43 0AL, Beds, England
[2] Natl Univ Singapore, Dept Mech Engn, Singapore 117576, Singapore
[3] Ultralife Corp, Ultralife Batteries Brand, Newark, NY 14513 USA
关键词
Primary lithium batteries; Fluorinated graphite; Carbon coating; Electrochemistry; Discharge;
D O I
10.1016/j.jpowsour.2009.10.096
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The electrochemical performances of fluorinated graphite have been improved by coating a uniform carbon layer on commercial CF(x) (x = 1) powder used as cathode material in lithium battery. In comparison with the cell using un-coated CF(x) as cathode, the cell using carbon coated CF(x) cathode has a higher energy density and higher power density, particularly at higher discharge current rates (1C above). This is because the conductive carbon coating provides the exterior connectivity between particles for facile electron conduction, resulting in high rate performance. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:2914 / 2917
页数:4
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