Palladium-catalyzed naphthylation of acenaphthylene

被引：11

作者：

Dyker, Gerald ^{[1
]}

Merz, Klaus ^{[1
]}

Oppel, Iris M. ^{[1
]}

Muth, Enrico ^{[1
]}

机构：

[1] Ruhr Univ Bochum, Fak Chem, D-44780 Bochum, Germany

来源：

SYNLETT | 2007年 / 06期

关键词：

palladium; Heck reaction; polycyclic aromatic; hydrocarbons; annulated cyclopentadienes;

D O I：

10.1055/s-2007-970785

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A bisnaphthyl-substituted acenaphthylene is synthesized via two independent two-step procedures, Pd-catalyzed and classically with Grignard reagents. The subsequent dehydrocyclization stops after the first carbon-carbon bond formation, leading to an octacyclic pi-system as the main product.

引用

页码：897 / 900

页数：4

共 16 条

[1] A CASE OF 2-PI+2-PI-CYCLOADDITION OF 2 ENOLATE IONS AT AMBIENT-TEMPERATURE [J].