Silica coated single walled carbon nanotubes

被引:155
作者
Whitsitt, EA
Barron, AR [1 ]
机构
[1] Rice Univ, Dept Chem, Houston, TX 77005 USA
[2] Rice Univ, Ctr Nanoscale Sci & Technol, Houston, TX 77005 USA
关键词
D O I
10.1021/nl034186m
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Single walled carbon nanotubes (SWNTs) have been coated with silica by the addition of a silica/H2SiF6 solution to a surfactant-stabilized solution of SWNTs. The thickness of the coating is controlled by reaction time, while the coating of individual SWNTs versus small ropes is controlled by the choice of surfactant. Individual nanotubes encased by a silica coating show retention of the characteristic Raman fluorescence. Selective etching of the silica coating allows for the exposure of either one end of the tubes or the central section. Exposure of the ends results in the formation of spontaneous interconnects between isolated SWNTs.
引用
收藏
页码:775 / 778
页数:4
相关论文
共 24 条
[1]   Structure-assigned optical spectra of single-walled carbon nanotubes [J].
Bachilo, SM ;
Strano, MS ;
Kittrell, C ;
Hauge, RH ;
Smalley, RE ;
Weisman, RB .
SCIENCE, 2002, 298 (5602) :2361-2366
[2]  
Balavoine F, 1999, ANGEW CHEM INT EDIT, V38, P1912, DOI 10.1002/(SICI)1521-3773(19990712)38:13/14<1912::AID-ANIE1912>3.0.CO
[3]  
2-2
[4]   COBALT-CATALYZED GROWTH OF CARBON NANOTUBES WITH SINGLE-ATOMIC-LAYERWALLS [J].
BETHUNE, DS ;
KIANG, CH ;
DEVRIES, MS ;
GORMAN, G ;
SAVOY, R ;
VAZQUEZ, J ;
BEYERS, R .
NATURE, 1993, 363 (6430) :605-607
[5]   Gas-phase production of carbon single-walled nanotubes from carbon monoxide via the HiPco process: A parametric study [J].
Bronikowski, MJ ;
Willis, PA ;
Colbert, DT ;
Smith, KA ;
Smalley, RE .
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A, 2001, 19 (04) :1800-1805
[6]   Noncovalent sidewall functionalization of single-walled carbon nanotubes for protein immobilization [J].
Chen, RJ ;
Zhang, YG ;
Wang, DW ;
Dai, HJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (16) :3838-3839
[7]   Extreme oxygen sensitivity of electronic properties of carbon nanotubes [J].
Collins, PG ;
Bradley, K ;
Ishigami, M ;
Zettl, A .
SCIENCE, 2000, 287 (5459) :1801-1804
[8]  
Dresselhaus M. S., 1996, SCI FULLERENES CARBO
[9]  
Fu Q, 2002, NANO LETT, V2, P329, DOI 10.1021/n1025513d
[10]   Carbon nanotubes, buckyballs, ropes, and a universal graphitic potential [J].
Girifalco, LA ;
Hodak, M ;
Lee, RS .
PHYSICAL REVIEW B, 2000, 62 (19) :13104-13110