Intramolecular hydrogen bonding and excited state proton transfer in hydroxyanthraquinones as studied by electronic spectra, resonance Raman scattering, and transform analysis

被引:53
作者
Marzocchi, MP [1 ]
Mantini, AR [1 ]
Casu, M [1 ]
Smulevich, G [1 ]
机构
[1] Univ Florence, Dipartimento Chim, I-50121 Florence, Italy
关键词
D O I
10.1063/1.475417
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The scheme of energy levels previously proposed to describe dual excitation and emission associated to excited state intramolecular proton transfer (ESIPT) of some hydroxyanthraquinones (HAQ's) has been made more quantitative in the present paper. The zero-paint energy and the frequency of the nu(OH) mode for the HAQ's have been calculated on the basis of the Lippincott-Schroeder double-minimum potential for the O-H ... O hydrogen bond, The second derivative absorption (D-2) spectra show that the vibrational structures of the electronic excited state of HAQ's giving rise to ESIPT are characterized by the progression of the nu(OH) stretching mode. The nu(OH) mode in the ground state is observed as a very strong band in the vibrational structure of the short wavelength emission for HAQ's showing ESIPT. The combined resonance Raman band assignment of four hydroxyanthraquinones and transform analysis show that the visible transition involves the hydrogen bonded cycle and induces proton transfer in the excited state in most cases. On the basis of the isotopic effects, some vibrations of the hydrogen bended cycle, namely the nu(C=O), delta(C=O), nu(COH), and delta(OH), modest have been identified. The transform method, including the combined analysis of the absorption and D-2 spectra in terms of sum-over-states, was checked by directly deriving the displacement parameters (Franck-Condon factors) of 1,4-DHAQ from the high resolution free-jet spectrum. The values of the displacement parameters of the nu(OH) mode are quite large for the HAQ's showing ESIPT, while are negligible for 1,4-DHAQ. High values of the displacement parameters for the other vibrations of the hydrogen bonded cycle were found for all HAQ's. (C) 1998 American Institute of Physics.
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页码:534 / 549
页数:16
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