A new trivalent cationic conducting solid electrolyte with NASICON-type structure

被引：24

作者：

Tamura, S ^{[1
]}

Imanaka, N ^{[1
]}

Adachi, G ^{[1
]}

机构：

[1] Osaka Univ, Fac Engn, Dept Appl Chem, Suita, Osaka 5650871, Japan

来源：

SOLID STATE IONICS | 2000年 / 136卷

基金：

日本学术振兴会;

关键词：

scandium; trivalent; ion conductor; NASICON; phosphate;

D O I：

10.1016/S0167-2738(00)00552-X

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A new trivalent cation conducting solid electrolyte with the NASICON-type structure, Sc1/3Zr2(PO4)(3), was synthesized by a sol-gel method and trivalent cation conducting properties were investigated. The trivalent ion conductivity of Sc1/3Zr2(PO4)(3) was comparable to those of the trivalent ion conducting tungstates with the Sc-2(WO4)(3)-type structure and its conductivity at 600 degreesC is 1.06x10(-4) S cm(-1), which is 2.5 times as high as that of Al-2(WO4)(3). The Sc3+ cation migration in Sc1/3Zr2(PO4)(3) was directly demonstrated by a de electrolysis. (C) 2000 Elsevier Science B.V. All rights reserved.

引用

页码：423 / 426

页数：4

共 8 条

[1] FAST NA+-ION TRANSPORT IN SKELETON STRUCTURES [J].