Molecular interpenetration within the columnar structure of crystalline anilino-β-cyclodextrin

被引:39
作者
Liu, Y [1 ]
You, CC
Zhang, M
Weng, LH
Wada, T
Inoue, Y
机构
[1] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China
[2] ERATO, JST, Inoue Photochirogenesis Project, Toyonaka, Osaka 5650085, Japan
[3] Osaka Univ, Dept Mol Chem, Suita, Osaka 5650871, Japan
关键词
D O I
10.1021/ol000135+
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A single crystal of mono(6-anilino-6-deoxy)-beta-cyclodextrin was prepared, and its crystal structure was determined by X-ray crystallographic analysis, which clearly revealed that the anilino groups are consecutively included intermolecularly into the adjacent cyclodextrin cavities in the crystal, thus giving rise to a consolidated column, located on a 2(1)-screw axis.
引用
收藏
页码:2761 / 2763
页数:3
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