Tetrabenzoporphyrin semiconductor for transistor applications

被引:16
作者
Aramaki, S [1 ]
Sakai, Y [1 ]
Yoshiyama, R [1 ]
Sugiyama, K [1 ]
Ono, N [1 ]
Mizuguchi, J [1 ]
机构
[1] Mitsubishi Chem Grp Sci & Technol Res Ctr, Aoba Ku, Yokohama, Kanagawa 2278502, Japan
来源
ORGANIC FIELD-EFFECT TRANSISTORS III | 2004年 / 5522卷
关键词
organic semiconductor; field effect transistor; tetrabenzoporphyrin; precursor; X-ray diffraction;
D O I
10.1117/12.566540
中图分类号
TH7 [仪器、仪表];
学科分类号
0804 ; 080401 ; 081102 ;
摘要
An organic field effect transistor (FET) device based on a solution-processible tetrabenzoporphyrin (BP) has been developed. BP is derived from its precursor that is soluble in some organic solvents and gives an amorphous film of high quality by spin coating. A polycrystalline film of BP is obtained by thermal conversion of the precursor at about 200degrees C. The FET characteristics are found to largely depend on the purity, device structure, and fabrication process. The device performance was: mobility of 1.7 X 10(-2) cm(2)/Vs and on/off ratio of 10(5). We have also analyzed the crystal structure of BP and characterized its electronic and morphological properties.
引用
收藏
页码:27 / 35
页数:9
相关论文
共 20 条
[1]   High-performance, solution-processed organic thin film transistors from a novel pentacene precursor [J].
Afzali, A ;
Dimitrakopoulos, CD ;
Breen, TL .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (30) :8812-8813
[2]   Solution-processible organic semiconductor for transistor applications: Tetrabenzoporphyrin [J].
Aramaki, S ;
Sakai, Y ;
Ono, N .
APPLIED PHYSICS LETTERS, 2004, 84 (12) :2085-2087
[3]  
ARAMAKI S, 2003, ACTA CRYSTALLOGR
[4]   Organic field-effect transistors with high mobility based on copper phthalocyanine [J].
Bao, Z ;
Lovinger, AJ ;
Dodabalapur, A .
APPLIED PHYSICS LETTERS, 1996, 69 (20) :3066-3068
[5]   New air-stable n-channel organic thin film transistors [J].
Bao, ZA ;
Lovinger, AJ ;
Brown, J .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (01) :207-208
[6]   Tetra-phenyl porphyrin based thin film transistors [J].
Checcoli, P ;
Conte, G ;
Salvatori, S ;
Paolesse, R ;
Bolognesi, A ;
Berliocchi, A ;
Brunetti, F ;
D'Amico, A ;
Di Carlo, A ;
Lugli, P .
SYNTHETIC METALS, 2003, 138 (1-2) :261-266
[7]   Structural order in conjugated oligothiophenes and its implications on opto-electronic devices [J].
Fichou, D .
JOURNAL OF MATERIALS CHEMISTRY, 2000, 10 (03) :571-588
[8]   SYNTHESIS AND PROPERTIES OF DOPED MU-OXO(TETRABENZOPORPHYRINATO)GERMANIUM(IV) [J].
HANACK, M ;
ZIPPLIES, T .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (21) :6127-6129
[9]  
Herwig PT, 1999, ADV MATER, V11, P480, DOI 10.1002/(SICI)1521-4095(199904)11:6<480::AID-ADMA480>3.0.CO
[10]  
2-U