Polymeric two- and three-dimensional transition-metal complexes comprising supramolecular host-guest systems

被引：37

作者：

Decurtins, S ^{[1
]}

Schmalle, H ^{[1
]}

Pellaux, R ^{[1
]}

机构：

[1] Univ Zurich, Inst Anorgan Chem, CH-1057 Zurich, Switzerland

来源：

NEW JOURNAL OF CHEMISTRY | 1998年 / 22卷 / 02期

关键词：

D O I：

10.1039/a708322j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Based on a synthetic strategy, extended anionic, homo-and bimetallic oxalato-bridged transition-metal compounds with two-(2D) and three-dimensional (3D) connectivities can be synthesized and crystallized. Thereby, the choice of the templating counter ions will determine the crystal chemistry. The aim of this synthetic, supramolecular approach is to exploit host-guest solids, where each component contributes its own physical characteristics. The two entities could behave independently, resulting in composite properties, or they may interact in a synergistic way, potentially leading to new physical phenomena.

引用

页码：117 / 121

页数：5

共 14 条

[1] Chiral, three-dimensional supramolecular compounds: Homo- and bimetallic oxalate- and 1,2-dithiooxalate-bridged networks. A structural and photophysical study [J].

Decurtins, S ;

Schmalle, HW ;

Pellaux, R ;

Schneuwly, P ;

Hauser, A .

INORGANIC CHEMISTRY, 1996, 35 (06) :1451-1460

[2] A CONCEPT FOR THE SYNTHESIS OF 3-DIMENSIONAL HOMOMETALLIC AND BIMETALLIC OXALATE-BRIDGED NETWORKS [M(2)(OX)(3)](N) - STRUCTURAL, MOSSBAUER, AND MAGNETIC STUDIES IN THE FIELD OF MOLECULAR-BASED MAGNETS [J].

DECURTINS, S ;

SCHMALLE, HW ;

SCHNEUWLY, P ;

ENSLING, J ;

GUTLICH, P .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (21) :9521-9528

[3] A POLYMERIC 2-DIMENSIONAL MIXED-METAL NETWORK - CRYSTAL-STRUCTURE AND MAGNETIC-PROPERTIES OF ([P(PH)4][MNCR(OX)3])N [J].

DECURTINS, S ;

SCHMALLE, HW ;

OSWALD, HR ;

LINDEN, A ;

ENSLING, J ;

GUTLICH, P ;

HAUSER, A .

INORGANICA CHIMICA ACTA, 1994, 216 (1-2) :65-73

[4] Three-dimensional helical supramolecules - Elucidation of magnetic ordering for an antiferromagnetic phase [J].

Decurtins, S ;

Schmalle, HW ;

Pellaux, R ;

Huber, R ;

Fischer, P ;

Ouladdiaf, B .

ADVANCED MATERIALS, 1996, 8 (08) :647-&

[5] A ROOM-TEMPERATURE ORGANOMETALLIC MAGNET BASED ON PRUSSIAN BLUE [J].

FERLAY, S ;

MALLAH, T ;

OUAHES, R ;

VEILLET, P ;

VERDAGUER, M .

NATURE, 1995, 378 (6558) :701-703

[6]

Kahn O, 1993, MOL MAGNETISM

[7] PERSPECTIVES IN SUPRAMOLECULAR CHEMISTRY - FROM MOLECULAR RECOGNITION TOWARDS SELF-ORGANIZATION [J].

LEHN, JM .

PURE AND APPLIED CHEMISTRY, 1994, 66 (10-11) :1961-1966

[8] Ferrimagnetic mixed-valency and mixed-metal tris(oxalato)iron(III) compounds: Synthesis, structure, and magnetism [J].

Mathoniere, C ;

Nuttall, CJ ;

Carling, SG ;

Day, P .

INORGANIC CHEMISTRY, 1996, 35 (05) :1201-1206

[9]

MILLER JS, 1995, MOL CRYST LIQ CRYST, V271

[10] Electrochemically tunable magnetic phase transition in a high-T-c chromium cyanide thin film [J].

Sato, O ;

Iyoda, T ;

Fujishima, A ;

Hashimoto, K .

SCIENCE, 1996, 271 (5245) :49-51

← 1 2 →