Structural evidence for resonance-assisted O-H•••S hydrogen bonding

被引：34

作者：

Steiner, T ^{[1
]}

机构：

[1] Free Univ Berlin, Inst Kristallog, D-14195 Berlin, Germany

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 03期

关键词：

D O I：

10.1039/a707434d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

By far the shortest hydrogen bonds of the O-H ... S type occur in monothio-beta-diketones and related substances (H ... S distances 1.9-2.0 Angstrom); it is shown with crystal correlation techniques that this very short hydrogen bonding is facilitated by resonance assistance similar to that occurring in the oxygen analogues.

引用

页码：411 / 412

页数：2

共 11 条

[1] Resonance-induced hydrogen bonding at sulfur acceptors in R1R2C=C and R1CS2- systems [J].

Allen, FH ;

Bird, CM ;

Rowland, RS ;

Raithby, PR .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1997, 53 :680-695

[2]

ALLEN FH, 1993, CHEM DESIGN AUTOMATI, V8, P1

[3]

ALLEN FH, 1997, ACTA CRYSTALLOGR B, V53, P596

[4] INTRAMOLECULAR N-H-CENTER-DOT-CENTER-DOT-CENTER-DOT-O HYDROGEN-BONDING ASSISTED BY RESONANCE .3. STRUCTURAL STUDIES OF 1-KETONE-2-ARYLHYDRAZONE DERIVATIVES [J].

BERTOLASI, V ;

GILLI, P ;

FERRETTI, V ;

GILLI, G .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1994, 50 :617-625

[5] Resonance-assisted O-H center dot center dot center dot O hydrogen bonding: Its role in the crystalline self-recognition of beta-diketone enols and its structural and IR characterization [J].

Bertolasi, V ;

Gilli, P ;

Ferretti, V ;

Gilli, G .

CHEMISTRY-A EUROPEAN JOURNAL, 1996, 2 (08) :925-934

[6] EVIDENCE FOR RESONANCE-ASSISTED HYDROGEN-BONDING FROM CRYSTAL-STRUCTURE CORRELATIONS ON THE ENOL FORM OF THE BETA-DIKETONE FRAGMENT [J].

GILLI, G ;

BELLUCCI, F ;

FERRETTI, V ;

BERTOLASI, V .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (03) :1023-1028

[7] COVALENT NATURE OF THE STRONG HOMONUCLEAR HYDROGEN-BOND - STUDY OF THE O-H---O SYSTEM BY CRYSTAL-STRUCTURE CORRELATION METHODS [J].

GILLI, P ;

BERTOLASI, V ;

FERRETTI, V ;

GILLI, G .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (03) :909-915

[8] CRYSTAL AND MOLECULAR-STRUCTURE OF 3-MERCAPTO-1,3-DIPHENYLPROP-2-EN-1-ONE BY X-RAY AND NEUTRON-DIFFRACTION [J].

POWER, LF ;

TURNER, KE ;

MOORE, FH .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1976, (03) :249-252

[9] Unrolling the hydrogen bond properties of C-H center dot center dot center dot O interactions [J].

Steiner, T .

CHEMICAL COMMUNICATIONS, 1997, (08) :727-734

[10] LENGTHENING OF THE COVALENT O-H BOND IN O-H...O HYDROGEN-BONDS REEXAMINED FROM LOW-TEMPERATURE NEUTRON-DIFFRACTION DATA OF ORGANIC-COMPOUNDS [J].

STEINER, T ;

SAENGER, W .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE CRYSTAL ENGINEERING AND MATERIALS, 1994, 50 :348-357

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