Two new 1,3-diammonium-propane zinc hydrogen phosphates:: H3N(CH2)3NH3•Zn2(HPO4)2(H2PO4)2, with 12-ring layers, and H3N(CH2)3NH3•Zn(HPO4)2, with 4-ring ladders

被引：85

作者：

Harrison, WTA ^{[1
]}

Bircsak, Z ^{[1
]}

Hannooman, L ^{[1
]}

Zhang, ZG ^{[1
]}

机构：

[1] Univ Western Australia, Dept Chem, Nedlands, WA 6907, Australia

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 1998年 / 136卷 / 01期

基金：

澳大利亚研究理事会;

关键词：

D O I：

10.1006/jssc.1997.7665

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The solution-mediated syntheses, single-crystal structures, and some physical properties of the first 1,3-diammonium-propane zinc phosphates, H3N(CH2)(3)NH3 . Zn-2(HPO4)(2)(H2PO4)(2) and H3N(CH2)(3)NH3 . Zn(HPO4)(2), are described. Both phases contain vertex-sharing ZnO4 and (H-2/H)PO4 tetrahedra, accompanied by doubly protonated organic cations. H3N(CH2)(3)NH3 . Zn-2(HPO4)(2)(H2PO4)(2) consists of a layered motif of infinite sheets of tetrahedral 12-rings, whereas H3N(CH2)(3)NH3 . Zn(HPO4)(2) is strongly one-dimensional and consists of tetrahedral 4-ring "ladders." Crystal data: H3N(CH2)(3)NH3 . Zn-2(HPO4)(2)(H2PO4)(2), M-r = 590.82, monoclinic, space group P2(1)/a (No. 14), a = 15.056(2) Angstrom, b = 7.8454(8) Angstrom, c = 16.344(2) Angstrom, beta=115.469(8)degrees, V=1742.9(3)Angstrom(3), Z=4, R(F)=5.17%, R-w(F)=5.68% [2859 observed reflections with I=3 sigma(1)]; H3N(CH2)(3)NH3 . Zn(HPO4)(2), M-r= 333.48, orthorhombic, space group P2(1)2(1)2(1) (No. 19), a = 5.2206(7) Angstrom, b = 12.717(2) Angstrom, c=15.570(2) Angstrom, V=1033.7(3)Angstrom(3), Z=4, R(F)=4.16%, R-w(F)=3.75% [1491 observed reflections with 1>3 sigma(I)]. (C) 1998 Academic Press.

引用

页码：93 / 102

页数：10

共 28 条

[1] SIR92 - a program for automatic solution of crystal structures by direct methods [J].

ALTOMARE, A ;

CASCARANO, G ;

GIACOVAZZO, G ;

GUAGLIARDI, A ;

BURLA, MC ;

POLIDORI, G ;

CAMALLI, M .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1994, 27 :435-435

[2]

BROWN ID, VALENCE PC VERSION

[3] Two three-dimensional tetrahedral framework zinc phosphates with infinite Zn-O-Zn chains: H[Zn-4(PO4)(3)]H2O and [Zn-4(H2O)(PO4)(3)] NH(CH3)(3) [J].

Bu, XH ;

Feng, PY ;

Stucky, GD .

JOURNAL OF SOLID STATE CHEMISTRY, 1996, 125 (02) :243-248

[4] The synthesis and characterization of a one-dimensional aluminophosphate: [C10N2H9] [Al(PO4)(PO2(OH)(2))] [J].

Chippindale, AM ;

Turner, C .

JOURNAL OF SOLID STATE CHEMISTRY, 1997, 128 (02) :318-322

[5] DESIGNED ASSEMBLIES IN OPEN FRAMEWORK MATERIALS SYNTHESIS - AN INTERRUPTED SODALITE AND AN EXPANDED SODALITE [J].

FENG, PY ;

BU, XH ;

STUCKY, GD .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1995, 34 (16) :1745-1747

[6] ON ENANTIOMORPH-POLARITY ESTIMATION [J].

FLACK, HD .

ACTA CRYSTALLOGRAPHICA SECTION A, 1983, 39 (NOV) :876-881

[7] PREPARATION AND CRYSTAL-STRUCTURE OF NA2ZN(HPO4)2.4H2O, A NEW LAYERED SODIUM ZINC PHOSPHATE-CONTAINING BIFURCATED TETRAHEDRAL 12-RINGS [J].

HARRISON, WTA ;

NENOFF, TM ;

GIER, TE ;

STUCKY, GD .

JOURNAL OF SOLID STATE CHEMISTRY, 1994, 113 (01) :168-175

[8] TETRAHEDRAL-ATOM ZINCOPHOSPHATE STRUCTURES - SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF 2 NOVEL ANIONIC 8-RING FRAMEWORKS CONTAINING CATIONIC 1,4-DIAZABICYCLO[2.2.2]OCTANE GUESTS [J].

HARRISON, WTA ;

MARTIN, TE ;

GIER, TE ;

STUCKY, GD .

JOURNAL OF MATERIALS CHEMISTRY, 1992, 2 (02) :175-181

[9] N(CH3)(4).ZnH3(PO4)(2): A large-pore zincophosphate built up from a 12-ring architecture with a remarkably low tetrahedral-framework-atom density [J].

Harrison, WTA ;

Hannooman, L .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1997, 36 (06) :640-641

[10] 'Template cooperation' effect leading to 18-ring cavities in the open-framework guanidinium zincophosphate (CN3H6)(3)Zn-7(H2O)(4)(PO4)(6)center dot H3O [J].

Harrison, WTA ;

Phillips, MLF .

CHEMICAL COMMUNICATIONS, 1996, (24) :2771-2772

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