Room temperature electrochemical opening of carbon nanotubes followed by hydrogen storage

被引:58
作者
Skowronski, JM
Scharff, P
Pfänder, N
Cui, S
机构
[1] Poznan Univ Tech, Inst Chem & Tech Electrochem, PL-60965 Poznan, Poland
[2] Tech Univ Ilmenau, Inst Phys, D-98693 Ilmenau, Germany
[3] Max Planck Inst Mol Genet, Fritz Haber Inst, D-14195 Berlin, Germany
[4] Tianjin Univ, Dept Chem, Tianjin 300072, Peoples R China
关键词
D O I
10.1002/adma.200390010
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
An electrochemical method is used to open multi-walled carbon nanotubes at a room temperature. HRTEM analysis (see Figure, arrows indicate openings) and cyclic voltammetry were undertaken and showed that, owing to the oxidation reactions occurring preferably at the end regions of nanotubes, an enhanced amount of hydrogen is stored in the nanotubes, which, during the cathodic reduction, is reversibly recovered.
引用
收藏
页码:55 / +
页数:4
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