Selective aromatic chlorination of activated arenes with sodium chlorite, (salen)manganese(III) complex, and alumina in dichloromethane

被引：23

作者：

Hirano, M ^{[1
]}

Yakabe, S ^{[1
]}

Monobe, H ^{[1
]}

Morimoto, T ^{[1
]}

机构：

[1] Tokyo Univ Agr & Technol, Fac Technol, Dept Appl Chem, Tokyo 184, Japan

来源：

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE | 1997年 / 75卷 / 12期

关键词：

aromatic chlorination; alkyl aryl ethers; sodium chlorite; (salen)manganese(III) complex; alumina;

D O I：

10.1139/v97-625

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of alkyl phenyl ethers with sodium chlorite in dichloromethane in the presence of a (salen)manganese(III) complex and alumina preloaded with a small amount of water afforded monochlorination products with unusually high para selectivities under mild conditions. The NaClO2-based biphasic system can also be successfully used for the regioselective monochlorination of substituted anisoles and polymethoxybenzenes.

引用

页码：1905 / 1912

页数：8

共 78 条

[1] ROLE OF WATER IN ALUMINA-ASSISTED SOLID-LIQUID INTERFACIAL REACTION [J].