Di- and trivalent dinuclear samarium complexes supported by pyrrole-based tetradentate Schiff bases

被引：42

作者：

Bérubé, CD

Gambarotta, S ^{[1
]}

Yap, GPA

Cozzi, PG

机构：

[1] Univ Ottawa, Dept Chem, Ottawa, ON K1N 6N5, Canada

[2] Dipartimento Chim G Ciamician, I-40126 Bologna, Italy

来源：

ORGANOMETALLICS | 2003年 / 22卷 / 03期

关键词：

D O I：

10.1021/om020773r

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions of [N(SiMe3)(2)](2)Sm(THF)(2) with three similar tetradentate pyrrole-based Schiff base ligands yielded three very different complexes. In two cases, an increase in the oxidation state was obtained via either ligand reductive coupling or disproportionation. The presence of a methyl substituent at the imine carbon atom instead prevented metal oxidation and afforded the first divalent samarium imine complex.

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页码：434 / 439

页数：6

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